George Clooney — Casamigos Tequila

George Clooney's Casamigos became the largest tequila acquisition in history when Diageo bought it for $1 billion. Clooney reportedly earned $233 million from the sale alone, which is 60% more than his entire film career earnings combined. The tequila's smooth taste drove rapid growth, surpassing #3 Kim Kardashian's SKIMS in per-unit profit margins. Clooney made more from agave than from Ocean's Eleven, Gravity, and every Nespresso ad put together.